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CCI Solar Events - From August 6 to 12, 2017 Pick date

1 PM

CCI Cybermeeting - Amit Das, Stahl Group - U. Wisconsin, Mad

01:00 PM to 02:00 PM, August 10, 2017

Electrochemical Generation and Reactivity of Molecular High-valent Iron-Oxo Species
Amit Das, Stahl Group 

High-valent iron-oxo species are key intermediates of heme and non-heme iron enzymes, selective oxidation catalysts, and they have been proposed recently in heterogeneous water oxidation catalyst.

We have recently begun exploring the generation of these high-valent iron-oxo complexes via proton-coupled oxidation of iron-aqua complexes investigating their comparative reactivity in two mechanistic distinct processes: water oxidation and C–H oxidation. Our initial efforts toward this end will be described.